Well this could get deep in the thick of it. Good thinking. I have owned a few weatherbys and see eye to eye with what you mention.
Couple theories -
1. Powder shape/size. We have a few that are fireballs, even through a silencer, that burns all the powder. 338 WSM does that with RL17 and an 18" barrel. The longer powders seem to do that. We use W748 in the 458 WSM. Have never seen a fireball out of that. CFE223 and H110, same thing. I think because of the shape of RL17 it is able to burn it all but at the last second. With tiny powders it is easier to finish it off at the muzzle without making a big show of it.
2. Where the powder is burned. Our sims and pressure sensors arn't quite advanced enough to show where this complete burn occurs. You think, o well it burns it all, thats optimum. Then you have a huge fireball and think you arn't. Call it a 24" barrel. It genereates pressure, we can see that at the muzzle and then down every inch to see a curve. I don't think that necessarily means that it burns perfectly even. You have 100 burning paper towel rolls that will catch fire and be thrust through a 10 foot PVC pipe. You have 2000 burning pieces of confetti that is thrust through the same pipe. Which is going to take longer to burn out when the atmosphere comes into play?
Naturally going with Weatherby ammo and load data, that is some high pressure awesome stuff. But they are known for twice the amount of free-bore as others. Bet their curves and test equipment show some Area 51 type firearm stuff.