You are probably already well on your way to solving the equation...but here is what I do:
Take one of the rounds you are trying to duplicate and pull the bullet out. Notice the type of powder (stick/ball, grain size, grain color or sheen, odor of the powder if any). Then weigh the powder from the pulled round. If its new production stuff, they print the expected velocity on the box and that should help alot too.
Compare your evidence to factory reloading manuals for the bullet weight of the round you are tying to duplicate (try the Hodgdon manual first if you think its 4350 or 4831). Just the charge weight, stated velocity and appearance of the powder will give you tons of info to compare.
Examples: 1. If it looks like 4350 and the charge weight lines up with the stated velocity and measured charge weight...viola. 2. You can probably tell the difference between 4831 and 4350 by just the charge weight and the velocity. 3. If it happened to be a different cartridge and were loaded with Varget or Benchmark or something...you will easily see the color and smell the difference in those powders.
Try this and you should be able to compare narrow it down a lot, if not precisely for factory ammo. I do it and it works. If you can't figure it out, take a picture of the powder and post it back here with the weight and the stated velocity from the box.